Sounds to me like the immobiliser is not disarming when you put the key in the ignition. There is a reset procedure which i'm sure someone will know off the top of their head (probably Reap) which may work.
putting the key in and pushing the plip button wont help.this only learns the radio part for the central locking(key resync)
sounds as though you have a physical problem with the micro chip in your key?.
if you put it in the ignition and open the door .does i bleep bleep to warn that you left your key in the ignition??.
i cant think for the life of me what system type it is but i have just decoded a citroen xsara 2002 with no problem i ve never been asked about bsi please educate / remind me
ecuclinic.com for repairs and decodes to most pugs